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2025
45. "Exploring the Synthesis and Properties of Fluorinated Cationic Triangulenes and Their Precursors" Kaur, R.; Hossain, Md M.; Shaikh, C. A.; Gianetti, T. L.;* Chem. Eur. J., 2025, e202404135
(Preprint on ChemRxiv)
44. "Modern organophotocatalysts: a new inspiration source for Symmetrical Organic Redox Flow Batteries" Moutet, J.; Hossain, Md M.; Kaur, R.; El Assaad, T. H.; Yual, W. K.; Amegatse, J. M.; Gianetti, T. L.;* ChemRixv , 2025, DOI: 10.26434/chemrxiv-2024-7fg0w
43. "Isolated Neutral Organic Radical Unveiled Solvent-Radical Interaction in Highly Reducing Photocatalysis" Shaikh, A. C.; Hossain, Md M.; Moutet, J.; Kumar, A.; Thompson, B.; Huxter, V. M.; Gianetti, T. L.;* Angew. Chem. Int. Ed., 2025, e202420483
(Preprint on ChemRxiv)
2024
41. "Designing the next generation of symmetrical organic redox flow batteries using helical carbocations" Moutet, J.; El Assaad, T. H.; Kaur, R.; Mills, D. D.; Gianetti, T. L.;* Energy Maters , 2024, 4:400024
40. "[4]Helicenium Ion as bipolar redox material for Symmetrical Fully Organic pole-less Redox Flow Battery" Moutet, J.; Mills, D. D.; Lozier, D. L.; Gianetti, T. L.;* Batteries & Supercaps , 2024, e202300519
2023
39. "Planar Carbenium Ions For Robust Symmetrical All Organic Redox Flow Battery" Moutet, J.; Nowack, MIlls, D. D.; Lozier, D. L.; M. H.; Laursen, B. W.; Gianetti, T. L. Mater. Adv., 2023,4, 4598-4606
38. "Triangulenium ions: Versatile Organic Photoredox Catalysts for Green-Light-Mediated Reactions" Nowack, M. H.; Moutet, J.; Laursen, B. W.; Gianetti, T. L.;* Synlett 2024; 35(03): 307-312
2022
37. "Green light to a green arylation" Hossain, M.; Gianetti, T. L.;* Trend in Chemistry, 2022, 4, 10, 962–963.
34. "Red-Light-Induced nPr-DMQA+-Catalyzed [3+2] Cycloaddition of Cyclopropylamines with Alkenes or Alkynes" Stull, S. M; Mei, L.; Gianetti, T. L.;* Synlett, 2022; 33(12): 1194-1198
(Preprint on ChemRxiv)
2021
33. "Synthesis of CF3-Containing Spirocyclic Indolines via a Red-Light-Mediated Trifluoromethylation / Dearomatization Cascade" Mei, L; Moutet, J.; Stull, S. M; Gianetti, T. L.;* J. Org. Chem. 2021, 86, 15, 10640-10653
2020
MENTORED PUBLICATIONS
24. “Synthesis and Characterization of Ion Pairs between Alkaline Metal Ions and Anionic Anti-Aromatic and Aromatic Hydrocarbons with π-Conjugated Central Seven- and Eight-Membered Rings” Jurt, P; Abels, A. S.; Gamboa-Carballo, J. J.; Fernández, I.; Le Corre, G.; Aebli, M.; Baker, M. G.; Eiler, F.; Müller, F.; Michael Wörle, M.; Verel, R; Gauthier, S.; Trincado, M.; T, Gianetti, T. L. Grützmacher, H. Angew. Chem. Intl. Ed. 2021, 10.1002/anie.202109642
23. “Synthesis and Characterization of Ion Pairs between Alkaline Metal Ions and Anionic Anti-Aromatic and Aromatic Hydrocarbons with π-Conjugated Central Seven- and Eight-Membered Rings”. Bloch, J.; Kradolfer, S.; Gianetti, T. L.; Ostendorf, D.; Day, S.; Mougel, V.; Grützmacher, H.,* Molecules, 2020, doi.org/10.3390/molecules25204742
22. “Trop-Based Homobimetallic Rh(I) Complexes: Influence of Ligands on the Structure and the Intramolecular Reactivity of Rh–H Intermediates”. Jurt, P; Salnikov, O. G.; Gianetti, T. L.;* Chukanov, N. V.; Baker, M. G.; Le Corre, G.; Verel, R.; Gauthier, S.; Kovtunov, K.; Federov, A.; Koptyug, I. V.; Grützmacher, H.,* Chem. Sci., 2019, 10, 7937-7945
21. “A low-valent dinuclear ruthenium diazadiene complex catalyzes the oxidation of dihydrogen and reversible hydrogenation of quinones” Yang, X.; Gianetti, T. L.;* Wörle, M. D.; Van Leest, N. P.; De Bruin, B.; Grützmacher, H.,* Chem. Sci., 2019, 10, 1117-1125
20. “Zero Valent Amino Olefin Cobalt Complexes as Catalysts for Oxygen Atom Transfer Reactions from Nitrous Oxide”. Gianetti, T. L.;* Rodriguez-Lugo, R. E.; Harmer, J.; Trincado, M., Vogt, M., Santiso-Quinones, G.; Grützmacher, H.,* Angew. Chem. Intl. Ed. 2016, 55, 15323-15328.
19. “From 0 to II in One Electron Steps: A Series of Ruthenium Complexes Supported by TropPPh2” Yang, X.; Gianetti, T. L.;* Harbort, J.; Wörle, M. D.; Tan, L.; Jurt, P.; Harmer, J. R.; Grützmacher, H.,* Angew. Chem. Intl. Ed, 2016, 55, 11999-12002.
18. "Nitrous Oxide as a Hydrogen Acceptor for the Dehydrogenative Coupling of Alcohols" Gianetti, T. L.;* Annen, S. P.; Santiso-Quinone, G.; Reiher, M.; Driess, M.; Grützmacher, H.,* Angew. Chem. Intl. Ed, 2016, 55, 1854-1858.
17. “Diolefins with an Ether/Thioether Functionality as Ligands in the Coordination Sphere of Ni and Rh” Lichtenberg, C.;* Bloch, J.; Gianetti, T. L.; Büttner, T., K.; Geier, J.; Grützmacher, H.,* Dalton Trans. 2016, 44, 20056-20066.
16. “Low-Valent Iron Mono-Diazadiene Compounds: Electronic Structure and Catalytic Application” Lichtenberg, C.;* Adelhardt, M.; Gianetti, T. L.; Meyer, K.; de Bruin, B.; Grützmacher, H.,* ACS Catalysis, 2015, 5, 6230-6240.
15. “Activation of Heteroallenes by Coordinatively Unsaturated Nickel(II) Alkyl Complexes Supported by the Hydrotris(3-phenyl-5-methyl)Pyrazolyl Borate (Tp(Ph,Me)) Ligand,” Abubekerov, M.; Eymann, L.; Gianetti, T. L.; Arnold, J.,* Dalton Trans. 2016, 45, 14581-14590.
14. “C–F sp2 Bond Functionalization Mediated by Niobium Complexes” Nechayev, M.; Gianetti, T. L.; Bergman, R. G.;* Arnold, J.,* Dalton Trans. 2015, 46, 19494-19500.
13. “Electron Localization in a Mixed-Valence Diniobium Benzene Complex” Gianetti, T. L.; Nocton, G.; Minasian, S. G.; Kaltzoyannis, N.; Kilcoyne, A. L. D.; Kozimor, S. A.; Shuh, D. K.; Tyliszczak, T.; Bergman, R. G.;* Arnold,* J., Chem. Sci. 2015, 6, 993-1003.
12. “Regioselective [2+ 2] and [4+ 2] Cycloaddition Reactivity in an Asymmetric Niobium (Bisimido) Moiety Towards Unsaturated Organic Molecules” Obenhuber, A.; Gianetti, T. L.; Bergman, R. G.;* Arnold, J.,* Chem. Comm. 2015, 51, 1278-1281.
11. “Synthesis and Characterization of Group 5 Imido Complexes Supported by the 2,6-Dichloroaryl-b-diketiminato Ligand” Nechayev, M.; Kriegel, B.; Gianetti, T. L.; Bergman, R. G.;* Arnold, J.,* Inorg. Chim. Acta 2014, 422, 114-119.
10. “Thorium lends a fiery hand” Arnold, J.;* Gianetti, T. L.; Kashtan, Y., Nat. chem. 2014, 6, 554.
9. “Stoichiometric Carbon–Carbon Bond Formation Mediated by Well-defined Nb (III) Complexes” Gianetti, T. L.; Bergman, R. G.;* Arnold, J.,* Polyhedron 2014, 84, 19-23.
8. “Reaction of (Bisimido) niobium (V) Complexes with Organic Azides:[3+ 2] Cycloaddition and Reversible Cleavage of β-Diketiminato Ligands Involving Nitrene Transfer” Obenhuber, A.; Gianetti, T. L.; Berrebi, X.; Bergman, R. G.;* Arnold, J.,* J. Am. Chem. Soc. 2014, 136, 2994-2997.
7. “Carbon–Fluorine Bond Cleavage in Fluoroarenes via a Niobium (III) Imido Complex: from Stoichiometric to Catalytic Hydrodefluorination” Gianetti, T. L.; Bergman, R. G.;* Arnold, J.,* Chem. Sci. 2014, 5, 2517-2524.
6. “Synthesis and Characterization of Coordinatively Unsaturated Nickel (II) and Manganese (II) Alkyl Complexes Supported by the Hydrotris (3-phenyl-5-methylpyrazolyl) Borate (TpPh, Me) Ligand" Abubekerov, M.; Gianetti, T. L.; Arnold, J.,* Dalton Trans. 2013, 42, 10525-10532.
5. “Group 5 Imides and Bis(imide) s as Selective Hydrogenation Catalysts” Gianetti, T. L.; La Pierre, H. S.; Arnold, J.,* Eur. J. Inorg. Chem. 2013, 22-23, 3771-3783.
4. “Dis-assembly of a Benzylic CF3 group mediated by a Niobium (III) Imido Complex” Gianetti, T. L.; Bergman, R. G.;* Arnold, J.,* J. Am. Chem. Soc. 2013, 135, 8145-8148.
3. “Diniobium Inverted Sandwich Complexes with µ-η6: η6-arene Ligands: Synthesis, Kinetics of Formation, and Electronic Structure” Gianetti, T. L.; Nocton, G.; Minasian, S. G.; Tomson, N. C.; Kilcoyne, A. L. D.; Kozimor, S. A.; Shuh, D. K.; Tyliszczak, T.; Bergman, R. G.;* Arnold, J.,* J. Am. Chem. Soc. 2013, 135, 3224-3236.
2. “Structures, Physicochemical Properties, and Reactivities of Cobalt (II) Complexes Supported by a Homoscorpionate (Tris(pyrazolyl)borate) Ligand” Kunishita, A.; Gianetti, T. L.; Arnold, J.,* Organometallics 2012, 31, 372-380.
1. “Z-selective, Catalytic, Internal-alkyne Semihydrogenation under H2:CO Mixtures by a Niobium(III) Imido Complex” Gianetti, T. L.; Tomson, N. C.; Arnold, J.;* Bergman, R. G.,* J. Am. Chem. Soc. 2011, 133, 14904 -14907.
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